Robust and digital hyper-polarization protocol of nuclear spins via magic sequential sequence

Hyper-polarization of nuclear spins is crucial for advancing nuclear magnetic resonance (NMR) and quantum information technologies, as nuclear spins typically exhibit extremely low polarization at room temperature due to their small gyro-magnetic ratios. A promising approach to achieving high nuclear spin polarization is transferring the polarization of electron to nuclear spin. The nitrogen-vacancy (NV) center in diamond has emerged as a highly effective medium for this purpose, and various hyper-polarization protocols have been developed. Among these, the pulsed polarization (PulsePol) method has been extensively studied due to its robustness against static energy shifts of the electron spin. In this study, we introduce a sequential polarization protocol and identify a series of magic and digital sequences for hyper-polarizing nuclear spins. Notably, we demonstrate that some of these magic sequences exhibit significantly greater robustness compared to the PulsePol protocol in the presence of finite half $\pi$ pulse duration of the protocol. This enhanced robustness positions our protocol as a more suitable candidate for hyper-polarizing nuclear spins species with large gyromagnetic ratios and also ensures better compatibility with high-efficiency readout techniques at high magnetic fields. Additionally, the generality of our protocol allows for its direct application to other solid-state quantum systems beyond the NV center.