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水系可充镁电池电解质的研究进展

中文摘要英文摘要

在全球能源转型与储能技术革新的大背景下,可充镁电池因其独特优势成为研究热点。该综述深入探讨了水系可充镁电池电解质的研究进展。传统有机电解质因易燃易爆和成本高而制约镁电池应用,水系电解质虽安全经济,但受狭窄电化学稳定窗口、副反应及负极钝化等问题限制。传统无机盐电解质因原料易得、成本低、离子电导率高而受关注,但电化学稳定窗口窄限制其性能提升;"盐包水"电解质通过高浓度设计拓宽电化学窗口,其复合体系及作用机理研究为性能优化提供新思路;共晶电解质因宽电化学窗口、高离子电导率等特性成为研究热点,电子结构调控可进一步扩展电化学窗口;凝胶电解质融合液态电解液与全固态电解质优点,适应柔性电子技术需求,其在低温、力学性能等方面的研究进展为实际应用提供技术支撑。

Under the global energy transition and energy storage innovation, rechargeable magnesium batteries have gained attention for their unique strengths. This review examines aqueous electrolyte advancements for such batteries. While traditional organic electrolytes pose safety and cost challenges, aqueous alternatives are safer and cheaper but limited by narrow electrochemical stability windows, side reactions, and anode passivation. Traditional inorganic salts offer affordability and high conductivity yet struggle with narrow stability. Water-in-salt electrolytes expand stability via high-concentration designs, with composite systems enhancing performance. Eutectic electrolytes excel in stability and conductivity, modifiable through electronic structure tuning. Gel electrolytes merge liquid and solid-state advantages, supporting flexible electronics with improved low-temperature and mechanical properties. Key challenges and future directions are outlined to advance practical applications.

周唯婷、李凌杰

重庆大学化学化工学院,重庆,401331重庆大学化学化工学院,重庆,401331

能源动力工业经济能源概论、动力工程概论

电化学可充镁电池电解质离子电导率柔性

ElectrochemistryRechargeable magnesium battery electrolytesIonic conductivityFlexibility

周唯婷,李凌杰.水系可充镁电池电解质的研究进展[EB/OL].(2025-05-22)[2025-05-24].http://www.paper.edu.cn/releasepaper/content/202505-137.点此复制

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