Spin vs. position conjugation in quantum simulations with atoms: application to quantum chemistry
Spin vs. position conjugation in quantum simulations with atoms: application to quantum chemistry
The permutation symmetry is a fundamental attribute of the collective wavefunction of indistinguishable particles. It makes a difference for the behavior of collective systems having different quantum statistics but existing in the same environment. Here we show that for some specific quantum conjugation between the spin and spatial degrees of freedom the indistinguishable particles can behave similarly for either quantum statistics. In particular, a mesoscopically scaled collection of atomic qubits, mediated by optical tweezers, can model the behavior of a valent electronic shell compounded with nuclear centers in molecules. This makes possible quantum simulations of mono and divalent bonds in quantum chemistry by manipulation of up to four bosonic atoms confined with optical microtraps.
N. A. Moroz、K. S. Tikhonov、L. V. Gerasimov、A. D. Manukhova、I. B. Bobrov、S. S. Straupe、D. V. Kupriyanov
Quantum Technology Centre, M.V. Lomonosov Moscow State UniversitySt. Petersburg State University and Russian Quantum CenterQuantum Technology Centre, M.V. Lomonosov Moscow State UniversityDepartment of Optics, Palacky UniversityQuantum Technology Centre, M.V. Lomonosov Moscow State UniversityQuantum Technology Centre, M.V. Lomonosov Moscow State UniversityQuantum Technology Centre, M.V. Lomonosov Moscow State University
物理学化学
N. A. Moroz,K. S. Tikhonov,L. V. Gerasimov,A. D. Manukhova,I. B. Bobrov,S. S. Straupe,D. V. Kupriyanov.Spin vs. position conjugation in quantum simulations with atoms: application to quantum chemistry[EB/OL].(2025-05-30)[2025-07-16].https://arxiv.org/abs/2505.24366.点此复制
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