Stochastic thermodynamics for classical non-Markov jump processes
Stochastic thermodynamics for classical non-Markov jump processes
Stochastic thermodynamics investigates energetic/entropic bounds in small systems, such as biomolecular motors, chemical-reaction networks, and quantum nano-devices. Foundational results, including the second law and thermodynamic uncertainty relations, predominantly rely on the Markov assumption -- neglecting history dependence of physical systems. However, while physicists recognise that the Markov assumption is dubious in real experimental setups, extending stochastic thermodynamics to general non-Markov systems has proven challenging due to their mathematical complexity. Here we establish the general theory of stochastic thermodynamics for arbitrary classical non-Markov jump processes. We introduce a key technique, called the {\it Fourier embedding}, which converts any non-Markov jump process into the Markov field dynamics of auxiliary Fourier modes. This approach yields the necessary and sufficient condition for time-reversal symmetry and enables the derivation of the second law for our non-Markov systems. Our framework accommodates diverse non-Markovian dynamics in realistic experimental setups and offers a guiding principle for physics-informed modelling of history-dependent fluctuations.
Kiyoshi Kanazawa、Andreas Dechant
物理学非线性科学
Kiyoshi Kanazawa,Andreas Dechant.Stochastic thermodynamics for classical non-Markov jump processes[EB/OL].(2025-06-05)[2025-06-16].https://arxiv.org/abs/2506.04726.点此复制
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