热处理温度对花生壳基多孔炭电化学性能影响的研究
以花生壳作为原材料,KOH为活性剂,采用炭化--活化法制备花生壳基多孔炭,在制备的工艺中通过改变活化温度,来对多孔炭的结构进行调控。使用扫描电镜、氮气等温吸附对样品进行了表征分析,并对花生壳多孔炭作为电极材料的电容器进行了电化学测试。采用恒电流充放电、循环伏安、交流阻抗和循环使用寿命对以多孔炭为电极材料的电容器进行电化学测试。结果表明,所制备的多孔炭具有丰富的孔隙结构,而且具有良好的电化学性能。最终温度为600 oC得到的样品PE-600在0.1 A g-1的条件下,比电容器为325F g-1,电流密度增加到5 A g-1,比电容仍保持253 F g-1,表明其具有良好的倍率性能。并且在5 A g-1电流密度的条件下循环4000次,比电容能够保持为原来的96.6%,说明具有良好的循环性能。
Using peanut shell as raw material and KOH as active agent, the structure of porous carbon in peanut shell was regulated by changing the final temperature by carbonization-activation method. The samples were characterized by scanning electron microscopy and nitrogen isothermal adsorption, and the capacitors with porous carbon in peanut shells as electrode materials were electrochemically tested. The electrochemical test of capacitors with porous carbon as electrode material was carried out by using galvanostatic charge-discharge, cyclic voltammetry, AC impedance and cyclic life. The results show that the prepared porous carbon has abundant pore structure and good electrochemical properties, and the final temperature of 600 oC obtained sample PE-600 is at the level of 0.1 A g-1, the current density increases to 5 A g-1, and the specific capacitance still maintains the performance of 253 F g-1, which proves that it has good rate performance, and cycles 4000 times under the condition of 5 A g-1 current density. The specific capacitance is maintained at 96.6%, which is further evidence of its excellent cycling stability.
吴燕、徐卫、李炎旭、汪燕、崔秀云、葛美红
黄山学院化学化工学院,黄山,245041黄山学院化学化工学院,黄山,245041黄山学院化学化工学院,黄山,245041黄山学院化学化工学院,黄山,245041黄山学院化学化工学院,黄山,245041黄山学院化学化工学院,黄山,245041
电化学工业
电化学多孔炭电容器花生壳粉电化学性能
ElectrochemistryPorous carbonCapacitorsPeanut shellElectrochemical performances
吴燕,徐卫,李炎旭,汪燕,崔秀云,葛美红.热处理温度对花生壳基多孔炭电化学性能影响的研究[EB/OL].(2025-07-08)[2025-07-25].http://www.paper.edu.cn/releasepaper/content/202507-8.点此复制
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