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What are we talking about when we discuss the Born-Oppenheimer approximation?

What are we talking about when we discuss the Born-Oppenheimer approximation?

来源:Arxiv_logoArxiv
英文摘要

Nick Huggett, James Ladyman, and Karim Thebault (HLT) have presented a comprehensive article examining the Born-Oppenheimer Approximation (BOA). Their central objective is to challenge our position on the matter-namely, that the BOA incorporates a classical assumption incompatible with the Heisenberg Uncertainty Principle. In contrast, HLT contend that the BOA involves no such classical assumption and, as a result, supports the view that chemistry can be reduced to physics. The purpose of this paper is to offer a critical analysis of the HLT article and to clarify why we consider their arguments unpersuasive.

Olimpia Lombardi、Sebastian Fortin、Juan Camilo Martinez Gonzalez、Hernan Lucas Accorinti

物理学化学

Olimpia Lombardi,Sebastian Fortin,Juan Camilo Martinez Gonzalez,Hernan Lucas Accorinti.What are we talking about when we discuss the Born-Oppenheimer approximation?[EB/OL].(2025-07-16)[2025-08-10].https://arxiv.org/abs/2507.12223.点此复制

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