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Fundamental measure theory for predicting many-body correlation functions

Fundamental measure theory for predicting many-body correlation functions

来源:Arxiv_logoArxiv
英文摘要

We study many-body correlation functions within various Fundamental Measure Theory (FMT) formulations and compare their predictions to Monte Carlo simulations of hard-sphere fluids. FMT accurately captures key features of three- and four-body structure, particularly at low and intermediate wavevectors. We show that the dominant contributions to the four-point structure factor arise from direct triplet correlations, allowing evaluation of four-point correlations to be greatly simplified. In glass-forming liquids at high volume fractions, FMT correctly reproduces deviations from the convolution approximation, highlighting FMT's ability to capture growing structural multipoint correlations upon supercooling.

Ilian Pihlajamaa、Teunike A. van de Pol、Liesbeth M. C. Janssen

物理学

Ilian Pihlajamaa,Teunike A. van de Pol,Liesbeth M. C. Janssen.Fundamental measure theory for predicting many-body correlation functions[EB/OL].(2025-08-20)[2025-09-02].https://arxiv.org/abs/2508.14642.点此复制

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