以Te纳米棒为模板的一维纳米结构Sb2Te3的制备与热电性能研究
ontrol synthesis and Thermoelectric Characterization of Sb2Te3 One-Dimensional Nanostructures Using Te Nanorods as Templates
本文中以Te纳米棒为模板采用两步法合成了Sb2Te3纳米棒。通过调整反应过程制备出大量无杂质的多晶Sb2Te3纳米棒;通过调控反应条件,以Te纳米棒为前驱体制备合成了Sb2Te3纳米串。反应溶液中未完全耗尽的K2TeO3与Sb3+离子发生反应,模板表面的Sb2Te3纳米片通过成核以及外延生长形成了纳米串。测量了Sb2Te3纳米棒的热电输运性质,发现样品的塞贝克系数增强,热导率降低,电阻率较高。
In this paper, we have demonstrated a two-step method to synthesize Sb2Te3 nanorods by using Te nanorods as the self-sacrificed templates. Impurity-free poly-crystalline Sb2Te3 nanorods have been synthesized on a large scale. Strings of Sb2Te3 nanoplatelets have been also synthesized by adjusting the reaction condition for Te nanorod precursor,which may be attributed to the nucleation and epitaxial growth of the Sb2Te3 nanoplatelets on the surface of the templates by the reaction of unconsumed K2TeO3 with Sb3+ ions in the solution. The thermoelectric transport properties of the pressed Sb2Te3 nanorods sample were measured. Enhanced seebeck coefficient and reduced thermal conductivity were observed. The high resistivity of the sample may be ascribed to unoptimized interconnections.
赵浩婷、朱航天、李冠男
能源动力工业经济热力工程、热机物理学
热电一维纳米结构碲化物
hermoelectricOne-dimensionalNanostructureTelluride
赵浩婷,朱航天,李冠男.以Te纳米棒为模板的一维纳米结构Sb2Te3的制备与热电性能研究[EB/OL].(2018-07-06)[2025-08-10].http://www.paper.edu.cn/releasepaper/content/201807-21.点此复制
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