无定形碳/二氧化锡复合纳米球锂离子电池负极性能研究
/SnO2 nanospheres as anodes of lithium ion battery
本文通过两步水热过程合成了无定形碳/二氧化锡复合纳米球结构。将其作为锂离子电池的负极,与纯的二氧化锡纳米球比较,该材料表现出更高的可逆容量和更稳定的循环性能。在C/5的倍率下,20个循环后,碳/二氧化锡复合纳米球的可逆容量能保持在743.6 mAh/g,这主要归因于无定形碳的良好导电性和充放电过程中的二氧化锡纳米球的抑制效应。该研究结果暗示着无定形碳/二氧化锡复合纳米球在锂离子电池负极方面具有潜在的应用价值。
In this paper, amorphous carbon/SnO2 hybrid nanospheres have been synthesized by a two-step hydrothermal process. As the anode material of lithium ion battery, C/SnO2 hybrid nanospheres exhibit higher reversible capacity and better cycling performance than pure SnO2 nanoshperes. After 20th cycle, the reversible capacity of C/SnO2 hybrid nanospheres maintains at 743.6 mAh/g at C/5 rate. The enhanced performance can be attributed to good conductivity of amorphous carbon and the suppression effect for SnO2 nanospheres during charge/discharge processes. The present results indicate that amorphours carbon/SnO2 hybrid nanospheres have potential applications in the anode of lithium ion battery.
薛欣宇、聂玉鑫
能源动力工业经济
纳米材料无定形碳二氧化锡锂离子电池负极
nanomaterialsamorphous carbontin oxidelithium ion batteryanode
薛欣宇,聂玉鑫.无定形碳/二氧化锡复合纳米球锂离子电池负极性能研究[EB/OL].(2014-12-26)[2025-08-18].http://www.paper.edu.cn/releasepaper/content/201412-807.点此复制
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