场激活合成Mg2Si热电性能研究
hermoelectric Properties of Mg2Si Prepared
用Mg粉和Si粉通过场激活加压辅助法(Field-activated and Pressure-assisted Synthesis,FAPASA),在1073K、50Mpa条件下快速实现了Mg2Si块体热电材料的一步合成与致密化;实验中反应物反应完全,产物中Mg2Si峰型尖锐,Mg2Si含量占产物含量的99.5%。合成样品的Seebeck系数、电导率、功率因子分别在562K、773K 、600k时达到最大值,分别为445µVK-1、54.4 Scm-1、4.35 W/cmK2。通过对比多种方法合成Mg2Si热电材料的热点性能发现,FAPAS样品的功率因子比其它方法具有明显的优势。
Bulk Thermoelectric material Mg2Si was synthesized and compected speedy in one step by Field-activated and Pressure-assisted at 1073 K 、50MPa for 15min using Mg and Si powders as raw material. It was found that Mg2Si peak is the only clear peaks there is no residual Si or Mg peak in the XRD pattern of FAPASA sample. The content of Mg2Si was about 99.5%. The Optical value of Seebeck coefficient α and electrical conductivity σ of the FAPASA samples were 445µVK-1, 54.4Scm-1 were obtained at the temperature of 562 K and 773K respectively. the highest power factor, 4.35×10-6W/cmK2 at 600 K, was obtained from the calculation from the Seebeck coefficients and electrical conductivity of sample. Compared with other synthesize methods, the FAPASA sample can achieve a higher power factor.
李柏松、陈超、孟庆森
材料科学
热电材料Mg2Si场激活压力辅助合成热电效应
thermoelectric materialMg2Sifield-activated pressure-assisted synthesisthermoelectric
李柏松,陈超,孟庆森.场激活合成Mg2Si热电性能研究[EB/OL].(2009-02-17)[2025-08-03].http://www.paper.edu.cn/releasepaper/content/200902-834.点此复制
评论