|国家预印本平台
首页|通过变形促进析出的θ'近似相提高Al-Cu合金的力学性能

通过变形促进析出的θ'近似相提高Al-Cu合金的力学性能

Mechanical properties enhanced by deformation-modified precipitation of θ'-phase approximants in an Al-Cu alloy

中文摘要英文摘要

用显微硬度测试、拉伸实验、TEM和ADF-STEM等检测手段研究了大的预变形对Al-Cu合金时效硬化,力学性能和显微结构的影响。结果表明,在后续时效过程中,经过80%冷轧变形的合金比传统T6工艺制备的Al-Cu合金强度提高了35%,并且塑性得到了很好的保持。在后续150 ℃时效后,合金中仍然保留有冷轧过程引入的大量位错。一般认为冷轧Al-Cu合金中高密度位错墙和位错缠结将会导致材料微观结构不均匀性,但是这种沿基体{001}面析出的的盘片状相却表现出非常均匀的分布。ADF-STEM观察发现这种析出相与θ'相晶体结构类似,但是其在体心位置的Cu原子是缺失的,本文称之为θ'-近似相。此外,析出相尺寸相比T6峰值的样品明显细化。这种形变改性的析出可能对合金的强度-塑性协同效应至关重要。

he effect of large pre-deformation on the age hardening behaviors, tensile properties and precipitate characteristics in an Al-Cu alloy during artificial ageing have been investigated using mechanical property measurements and electron microscopy. It is shown that a room-temperature rolling of Al-Cu alloy with a thickness reduction of 80% plus a subsequent artificial ageing can result in a strength increase by 35% without sacrificing ductility, with respect to that of the alloy peak-aged by a conventional heat treatment process (T6). After post-ageing at 150 oC, a large quantity of dislocations accumulated during cold-rolling is retained in Al-Cu alloy. Though dense dislocation walls and dislocation tangles existed in cold-rolled Al-Cu alloy were expected to result in micro-structural heterogeneity, the plate-shaped precipitates on {001}Al planes exhibit an exceptionally uniform distribution. Atomic-scale angular dark-field scanning transmission electron microscopy (ADF-STEM) reveals these precipitates are θ'-approximants with a crystal structure similar with the well-known tetragonal θ' phase but with the absence of Cu atom at the body-centered position. In addition, the precipitate sizes are considerably refined as compared to the θ' precipitates formed in T6 peak-aged alloys. Our results suggest the deformation-modified precipitation may play a vital role in achieving better strength-ductility synergy.

刘力梅、刘春辉、马培培、陈江华、伍翠兰、赖玉香

材料科学金属压力加工金属学、热处理

l-Cu合金析出相形变时效透射电镜

l-Cu alloysPrecipitationDeformationAgeingTransmission electron microscopy

刘力梅,刘春辉,马培培,陈江华,伍翠兰,赖玉香.通过变形促进析出的θ'近似相提高Al-Cu合金的力学性能[EB/OL].(2017-05-17)[2025-08-23].http://www.paper.edu.cn/releasepaper/content/201705-1080.点此复制

评论