亲疏水效应对微型直接甲醇燃料电池的影响
Hydrophilicity effect on micro-scale flow of micro DMFC
能否将阳极产物CO2有效地排出阳极微流道决定了微型直接甲醇燃料电池的性能。本文采用Lattice-Boltzmann模型来模拟亲疏水沟道内的二相流体流动情况,考虑了液-气表面张力,流体-固体相互作用和浮力。仿真结果显示,亲水沟道中CO2的排放速度比在疏水沟道中快。为验证仿真结果,我们设计制造了有效面积1.0 cm2的微型直接甲醇燃料电池,并进行了相应的测试。测试结果显示,亲水沟道改善了气体排放和甲醇供应状况,使得亲水沟道的μDMFC的能量密度峰值比疏水沟道的μDMFC的能量密度高出15.7%,而其最高电流密度值低于疏水沟道的μDMFC。
he effective removal of carbon dioxide (CO2) in the anode micro channels is critical to the performance of the micro direct methanol fuel cell (μDMFC). A Lattice-Boltzmann model coupled with liquid-gas surface tension, fluid-solid interaction and buoyancy force is adopted in this work to simulate the two-component flow with different hydrophilicity channels. The simulation results show that the emission speed of CO2 gas in the cell patterned with the hydrophilic channel wall is faster than that with the hydrophobic wall. In order to mutually validate the simulation results, a μDMFC with an active area of 1.0 cm2 is designed, fabricated, and tested. Data results show that with improved gas expelling and fuel supplying, the novel μDMFC with the hydrophilic flow field gets an increase of 15.7% in peak power density and a dramatically lowered polarization at high current density output.
王紫、刘晓为、张宇峰
能源动力工业经济氢能、氢能利用
微型直接甲醇燃料电池,亲水沟道,气泡动态
Micro direct methanol fuel cell micro sized configuration current collector
王紫,刘晓为,张宇峰.亲疏水效应对微型直接甲醇燃料电池的影响[EB/OL].(2014-01-08)[2025-08-16].http://www.paper.edu.cn/releasepaper/content/201401-392.点此复制
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