表面微观结构对液滴浸润的影响特性
nalysis of wetting characteristics on microstructured hydrophobic surfaces
利用聚二甲基硅氧烷(PDMS)制备了微方柱结构疏水表面,分析了微方柱间距和高度对液滴表面浸润特性的影响。研究发现,随着微方柱间距的增大,粗糙表面表观接触角越大,但由于间距增大导致粗糙度下降,而平滑PDMS表面的表观接触角较小,因此势必存在一个最佳的微方柱间距,使表观接触角取得最大值。同时对不同高度微方柱结构疏水表面液滴浸润特性的研究表明:在微方柱间距和边长一定时,微方柱高度对液滴的初始浸润状态影响较小,但对液滴浸润状态的稳定性影响很大,当微方柱高度较大时,液滴的浸润状态相对较为稳定,而微方柱高度较低时,液滴会出现接触角突然减小的"坍塌",由近似Cassie状态转变成Wenzel状态;分析认为,应存在一个临界高度,在低于临界高度时,初始液滴在一段时间后会突然"坍塌",而高于临界高度时,液滴的浸润状态则相对稳定。
he pillar-structured hydrophobic surfaces were prepared with the polydimethyl-siloxane (PDMS) substrate using photolithography techniques. The wettability of the hydrophobic surfaces with different microstructure spacing and height were studied. Experimental results show that the contact angle will increase when the microstructure spacing increase. Howerer, the roughness decrease when the microstructure spacing increases and the contact angle on smooth surfaces is small. So there must be existing a critical microstructure spacing at which the contact angle on the hydrophobic surface achieves the biggest value. Furtherfore, the contact angle on the hydrophobic surfaces with different micropillar height. The results showed that the micropillar height has little influence on initial wetting characteristics but has great influence on the stability of wetting status. The micropillar height greater, the wetting status of the droplet is more steady. When the microstructure height is small, the wetting statues are not steady. Therefore, a critical micropillar height must be existed. The wetting status are steady when the micropillar heights are higher than the critical height and the droplets will suddenly collapse when the micropillat heights are small than the critical height. .
雷威、贾志海、贺吉昌、蔡泰民
材料科学
微结构表面间距高度浸润特性
microstructuresurfacespacingheightwetting characteristics
雷威,贾志海,贺吉昌,蔡泰民.表面微观结构对液滴浸润的影响特性[EB/OL].(2013-12-19)[2025-08-16].http://www.paper.edu.cn/releasepaper/content/201312-538.点此复制
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