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木薯淀粉硫酸酯理化性能的研究

Research on Structures and Properties of Cassava Starch Sulfate Esters

中文摘要英文摘要

以NaHSO3和NaNO2作为酯化剂,水相法制备了低取代度的淀粉硫酸酯(SSE),通过测定SSE糊的冻融稳定性、凝沉性能、透明度、粘度,以及pH值和NaCl用量对糊粘度的影响。结果表明,酯化后糊透明度比原淀粉提高22.4%,透明度稳定性明显增强;粘度冷热差值均低于原淀粉,抗老化性增强,凝沉性能减弱,且糊的冻融稳定性优于原淀粉;SSE糊的粘度在碱性环境中变化不大,但随着酸性的增大而逐渐下降,且较高取代度SSE糊的耐酸性优于低取代度SSE;NaCl用量的增加对SSE糊的粘度影响小。利用红外光谱仪对产物的结构进行了表征,产品分别在1346cm-1和1186 cm-1呈现硫酸基团的特征吸收峰。

he low degree of substitution of starch sulfate ester (SSE) was synthesized in aqueous solution from cassava starch with the esterification agent like NaHSO3 and NaNO2, the properties of SSE paste were determined by its freeze-thaw stability, anti-aging capacity, transparency and viscosity, and the influence of pH value and the medium NaCl on the paste viscosity.The conclusions showed that, after esterification, the transparency of the SSE was increased by 22.4% , the viscosity of SSE paste was higher, the transparency stability was enhanced, and the retrogradation trend was weakened, as for the freeze-thaw stability as well as the storage stability improved. The SSE paste viscosity changed slightly in an alkaline condition, but gradually descended with the increase of acidity, as for the acid-resistant performance, the SSE with high DS was superior to that with low DS; while NaCl had little effect on the viscosity characteristics of SSE starch pastes, the FT-IR showed that 1346cm-1 and 1186 cm-1 were the characteristic absorption peaks of sulfate groups.

张友全、刘绍秀、玉琼广

生物化学生物工程学高分子化合物工业

木薯淀粉硫酸酯低取代度理化性质结构表征

cassava starch sulfate esterlow degree of substitutionphysicochemical propertystructure characterization

张友全,刘绍秀,玉琼广.木薯淀粉硫酸酯理化性能的研究[EB/OL].(2011-02-15)[2025-08-10].http://www.paper.edu.cn/releasepaper/content/201102-137.点此复制

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