3-吲哚甲醛类席夫碱金属配合物的合成与表征
Synthesis and characterization of metal complexes with Schiff bases derived from indole-3-carboxaldehyde
席夫碱及其金属配合物在催化、功能材料、生物医学及分析化学等领域具有重要的应用前景。本文以海洋生物活性小分子3-吲哚甲醛为前驱体，分别与4-氨基水杨酸及4-氨基马尿酸反应生成席夫碱配体，并与过渡金属Cu(II)、Ni(II)及稀土金属Sm(III)盐共热，合成了五种新型的席夫碱金属配合物。利用元素分析、红外光谱分析、紫外光谱分析等多种分析测试手段对配合物的结构进行了表征。
Schiff bases and their metal complexes have wide applications in catalysis, function materials, biomedicine, and analytical chemistry, et al. In this paper, two Schiff bases (HL1 and HL2) were synthesized using a small marine active molecular indole-3-carboxaldehyde, 4-aminosalicylic acid and 4-aminohippuric acid. Five novel solid complexes of this two ligands with transition metals Cu(II), Ni(II) and rare earth metal Sm(III) ions have been prepared and characterized by elemental analyses, IR spectrum and UV spectrum, etc.
黄桂梅、范玉华、毕彩丰、张楠、闫星辰、张霞
无机化学工业精细化学工业
海洋活性小分子3-吲哚甲醛席夫碱配合物
Small marine active molecularSchiff base complexIndole-3-carboxaldehyde
黄桂梅,范玉华,毕彩丰,张楠,闫星辰,张霞.3-吲哚甲醛类席夫碱金属配合物的合成与表征[EB/OL].(2014-04-18)[2025-08-02].http://www.paper.edu.cn/releasepaper/content/201404-243.点此复制
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