长江口滨岸水体悬浮颗粒物多环芳烃的分布与来源
istribution and Origin of Polycyclic Aromatic Hydrocarbons in Suspended Particulate Matters from the Yangtze Estuarine and Coastal Areas
对长江口滨岸水体悬浮颗粒物中的多环芳烃(PAHs)进行了定量分析,结果显示悬浮颗粒物PAHs总量为2278.79-14293.98 ng/g,排污口附近浓度最高,远离排污口浓度降低;就其组成特征而言,以4-6环PAHs为主,2-3环PAHs相对较少;聚类分析表明除了城市排污外,河口水动力条件和盐淡水交互过程也对滨岸PAHs的分布具有重要影响。主成分分析和PAHs特征参数分析发现,滨岸水环境中PAHs的主要来源为矿物燃料的不完全燃烧,此外还有少量石油输入。生态风险评价结果显示,大部分PAH化合物均超过ER-L值和ISQV-L值,表明长江口滨岸水体悬浮颗粒物中的PAHs已具有不利的生物影响效应。
Parent PAHs have been quantified in suspended pariculate matters from the Yangtze Estuarine and Coastal Areas. The results show that the concentrations of total PAHs ranged from 2278.79-14293.98 ng/g, and were characterized by greatest content near sewage discharge point with trend to decrease by increasing distance. As for PAHs composition, 4-6 rings PAHs were dominant while 2-3 rings PAHs were relative low. Cluster analysis found that except urban sewage discharge, the hydrodynamic force and the process of freshwater and saltwater interaction in the Yangtze estuary also play the important roles in PAHs distribution. Principal component analysis and PAH ratios demonstrated that uncompleted combustion of fossil fuels was the main source of PAHs in coastal areas, as well as a few anthropogenic release of oil and oil products. Ecological risk assessment indicated that most of PAH compounds exceeded the effects range ER-L values and ISQV-L values, which might certain potentical damage to the Yangtze estuary ecosystem.
许世远、高磊、欧冬妮、刘敏、程书波
环境污染、环境污染防治
分布,来源,多环芳烃,悬浮颗粒物,长江口滨岸
distributionoriginPAHssuspended particulate mattersthe Yangtze Estuary
许世远,高磊,欧冬妮,刘敏,程书波.长江口滨岸水体悬浮颗粒物多环芳烃的分布与来源[EB/OL].(2007-12-21)[2025-08-02].http://www.paper.edu.cn/releasepaper/content/200712-540.点此复制
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