纳米级晶体缺陷诱发YBCO超导薄膜的强磁通钉扎性能
Strong Flux Pinning Induced by Nanodefects in YBCO Film Derived from Fluorine-free Chemical Solution Deposition
人们一直期盼YBCO薄膜在高温以及与其c轴成不同角度的磁场下均能表现出强烈的磁通钉扎性能以更好地满足涂层导体的高温、高场的实际应用要求。本文在BST微阵列缓冲的LAO单晶衬底上制备外延生长的YBCO薄膜,通过薄膜与衬底界面的异质外延应力诱导YBCO基体内部纳米尺寸晶体缺陷的形成。借助高分辨透射电子显微镜观察到高密度的晶体缺陷,包括纳米孪晶、交互生长、堆垛层错、晶面弯曲等。磁化强度随磁场的变化曲线测试结果显示,在外磁场与YBCO的c轴夹角为0?~90? 时YBCO薄膜的临界电流密度均有显著提升,说明这些晶体缺陷使YBCO薄膜显示出了准各向同性的涡旋钉扎特性。因此,无论通过什么方法,只要能在外延生长的YBCO薄膜内部引入一定数量的纳米晶体缺陷就能够大幅增强YBCO薄膜的磁通钉扎力,提高其在磁场下的载流能力。
It is commonly expected that there are strong vortex pinning force when YBa2Cu3O7-δ (YBCO) coated conductors are served at high temperature and different magnetic field orientations angled to YBCO c-axis. In this paper, we show a simple approach, epitaxially growing YBCO film on Ba0.7Sr0.3TiO3 (BST) microarrays buffered LaAlO3 (LAO) substrate, to introduce nanoscale crystalline defects within YBCO matrix. High concentration nanodefects, including nanotwins, intergrowth, stacking faults and plane buckling were observed by high-resolution transmission electron microscopy. It is demonstrated through magnetization vs. magnetic field strength measurement that these nanodefects can endow quasi-isotropic vortex pinning characteristic to nanostructured YBCO films to enable power applications of coated conductors. It is believed that nonsuperconductivity regions (the dimension near to the order of ξ, the coherence length of YBCO) caused by the nanodefects are the effective pinning centers to inhibit flux creep. Therefore, large pinning energy can be easily obtained for YBCO films if considerable nanodefects can be introduced into epitaxial YBCO matrix no mater what methods are employed to produce YBCO nanocomposite film.
刘露、赵高扬、王莎莎、王秀婷、雷黎
电工材料物理学材料科学
材料物理与化学YBCO薄膜涡旋钉扎化学溶液沉积纳米缺陷准各向同性
materials physics and chemistryYBCO filmsvortex pinningquasi-isotropynanodefectschemical solution deposition
刘露,赵高扬,王莎莎,王秀婷,雷黎.纳米级晶体缺陷诱发YBCO超导薄膜的强磁通钉扎性能[EB/OL].(2015-09-08)[2025-08-05].http://www.paper.edu.cn/releasepaper/content/201509-67.点此复制
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