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沉积时间对Al-Mg合金的形貌、组分和防腐性能的影响

Effects of electrolysis time on the surface morphology, composition and corrosion resistance of Al-Mg alloy coatings

中文摘要英文摘要

本文研究了在AlCl3-NaCl-KCl-MgCl2体系中,在钨丝表面电沉积Al-Mg合金镀层,作为Z-箍缩负载材料。通过扫描电子显微镜来观察表面形貌,能谱分析法仪分析镀层成分,光电子能谱分析镀层的价态,X射线衍射仪检测镀层的结构和对Al-Mg合金镀层进行交流阻抗测试检测其防腐性能。结果表明:随着电镀时间的增加镀层表面颗粒更加均匀,Mg含量有所提高。镀层的结构以面心立方的Al和非晶态的Al-Mg合金固溶体的形式存在。在3.5wt%NaCl溶液中,交流阻抗测试出Al-Mg合金镀层耐腐蚀性能随着电镀时间的增加也有所增强。

In this paper, Al-Mg alloy coatings were electroplated on tungsten wire surface in an inorganic molten salt AlCl3-NaCl-KCl-MgCl2 system for potential application in z-pinch experiments. Scanning electron microscope, energy spectrum and X-ray diffraction were used to characterize the surface morphology, composition, valence state of elements and crystal structure of the coatings. Ac impedance tests were employed to evaluate the corrosion protection performance. The results showed that the surface morphology of the electrodeposited Al-Mg alloy coating is smooth and the crystalline grains are uniform with the increase of the electrolysis time, and Mg content is also increased. The structures of the coatings are composed of the amorphous Al-Mg alloy solid solution and the Al crystal with a face-centered cubic structure. Al-Mg alloy coatings possessed an improved corrosion resistance with the increase of the electrolysis time based on the analysis of the electrochemical impedance spectroscopy in 3.5wt% NaCl solution. .

骆佳秋、尹嘉琳、张浩、胡文成

材料科学金属学、热处理有色金属冶炼

应用化学钨丝l-Mg合金电沉积交流阻抗

applied chemistryAl-Mg alloytungsten wireelectro-depositionelectrochemical impedance spectroscopy

骆佳秋,尹嘉琳,张浩,胡文成.沉积时间对Al-Mg合金的形貌、组分和防腐性能的影响[EB/OL].(2016-07-12)[2025-08-02].http://www.paper.edu.cn/releasepaper/content/201607-155.点此复制

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