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乙酰化木粉/聚烯烃木塑FDM线材的制备及性能研究

Investigation on the Preparation and Properties of Acetylated Wood Flour/Polyolefin based Wood Plastic Composite FDM Filaments

中文摘要英文摘要

以聚丙烯(PP)和线型低密度聚乙烯(LLDPE)作为基体,采用乙酰化改性木粉作为增强填料,与滑石粉、纳米SiO2等助剂球磨,通过单螺杆挤出法制备适于3D打印的木塑复合线材。考察了基体配比、乙酰化改性木粉含量对木塑复合材料性能的影响。利用差热-热重同步分析仪、热变形维卡软化点温度测定仪、熔体流动速率仪、万能力学试验机对所制材料的耐热性、流动性和力学性能进行了表征测试。结果显示:m(PP)/m(LLDPE)=35:65为适宜基体配比。随着乙酰化木粉含量的增加,复合材料的拉伸强度、弯曲强度、弯曲模量均呈先增大后减小的趋势。乙酰化木粉添加量为基体质量30wt%的木塑复合材料力学性能最优,其拉伸强度、弯曲强度、弹性模量分别为24.5MPa、23.3MPa、1023.3MPa。同时木粉的添加,提高了复合材料的热变形温度,当乙酰化木粉添加量为基体质量20wt%-30wt%时,木塑复合材料的热变形温度较高。对所制乙酰化木粉/聚烯烃木塑FDM线材进行了3D打印测试,结果表明,材料的耐热性、流动性和力学性能均可满足3D打印的要求。

wood plastic composites(WPC) filament for fused deposition molding(FDM) was prepared by ball milling and screw extruding a mixture of polypropylene(PP), linear low density polyethylene(LLDPE) matrix, acetylated wood flour (AWF), talcum powder, nano SiO2, and other additives. The influences of the matrix ratio and the wood powder ratio on the properties of materials were investigated. Thermal stability,fluidity, and mechanical properties were characterized by using simultaneous thermogravimetric-differential thermal analysis system, Vicat softening Point tester, melt flow rate meter, and universal mechanical testing machine. The testing results show that the optimum m(PP)/m(LLDPE) ratio is 35:65. With the increase of the weight percentage of AWF in the WPC, the tensile strength, flexural strength, flexural modulus of the WPC firstly increase and then decrease. The material prepared with 30wt% of AWF has the highest tensile strength (24.5 MPa), bending strength (23.3 MPa), and elastic modulus (1023.3 MPa). The addition of wood powder raised the heat deformation temperature of the WPC. When the material contains 20wt%~30wt% of AWF, the WPC has relatively higher deformation temperature. The prepared WPC filaments were tested on a 3D printer. The results indicate that the thermal stability, mechanical properties, and fluidity of the material meet the requirement of 3D printing.

范英姿、余贞梅、李湘洲、李文生、周小平

高分子化合物工业合成树脂工业、塑料工业木材加工工业、家具制造工业

木塑复合材料聚丙烯-线型低密度聚乙烯基体乙酰化木粉FDM线材单螺杆挤出力学性能

Wood-plastic compositesPP-LLDPE matrixacetylated wood flourFDM filamentsingle screw- extrusionmechanical properties

范英姿,余贞梅,李湘洲,李文生,周小平.乙酰化木粉/聚烯烃木塑FDM线材的制备及性能研究[EB/OL].(2017-05-31)[2025-08-21].http://www.paper.edu.cn/releasepaper/content/201705-1460.点此复制

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