两种卟啉类化合物的合成及电致发光性质

Preparation of a novel porphrin derivative bearing oligo(p-phenylene) group and its zinc complex was reported, which involved a microwave irradiation (MW) and a synthesis based on template effects, respectively. Both of the porphrin derivative and its zinc complex were fully characterized through IR, NMR and MALDI-TOF-MS. Optical properties (UV-Vis and fluorescence), and thermal stabilities were also studied for both compounds according to the spectra analysis, and TGA, respectively. For zinc complex the electrochemistry was study by CV. Further fabrication using the zinc complex as a dopant resulted an electroluminescent device emission at 556nm.