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丙烯酸树脂基导电油墨正/负升温系数协同效应的研究

Study on the positive and negative temperature coefficient synergistic effect of acrylic resin matrix conductive ink

中文摘要英文摘要

采用乳液聚合的方法,利用Fox方程进行设计合成了玻璃化温度可控型聚(甲基丙烯酸甲酯-丙烯酸丁酯)(P(MMA-BA))。利用差热扫描量热仪(DSC)测定了聚合物的玻璃化温度(Tg)。重点探讨了丙烯酸粘结料树脂玻璃化温度与导电填料的配比对电热膜电阻值稳定性的影响。利用扫描电子显微镜(SEM)观察分析导电网络。结果表明,非晶态丙烯酸高聚物的PTC效应显著,消除了导电填料在温度升高过程中的NTC效应。

In this paper,Glass transition temperature of polymers was designed by using Fox equation, and poly(methyl methacrylate-butyl acrylate) was synthesized by emulsion polymerization. The glass transition temperatures(Tg) of polymers were measured by means of a differential scanning calorimeter (DSC).The effects of the ratio of resin matrix to conductive materials on membrane stability were emphatically investigated. The results of experiments indicated that the performance of electrothermal membrane could be improved by adding appropriate conductive material, and the membrane stability is highly dependent on the ratio resin matrix to conductive material. Conductive net was studied by means of scanning electron microscopy(SEM). The results show that the PTC effect of amorphous acrylic polymer significantly, eliminate the NTC effect of conductive filler in the process temperature rise.

刘成岑、窦涛、李万捷、李晨光

电工材料高分子化合物工业合成树脂工业、塑料工业

玻璃化温度的设计丙烯乳液导电油墨电热膜正温度系数(Positive temperature coefficient)负温度系数(Negative temperature coefficient)

the design of glass transition temperatureacrylic emulsionconductive inkelectrothermal membranePTC(Positive temperature coefficient)NTC(Negative temperature coefficient)

刘成岑,窦涛,李万捷,李晨光.丙烯酸树脂基导电油墨正/负升温系数协同效应的研究[EB/OL].(2011-01-05)[2025-08-02].http://www.paper.edu.cn/releasepaper/content/201101-242.点此复制

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