自由基-悬浮聚合法制备苯乙炔均聚物和共聚物微球

In this work, we estabilished a new methodology for preparing phenylacetylene-derived homo- and co-polymer microspheres via free radical polymerization in aqueous systerms. FT-IR, 1H NMR and Raman spectroscopy techniques were used to characterize the products. SEM images demonstrated that the microspheres possessed excellent dispersibility and smooth surface. TGA was conducted to characterize the thermal stability of the polymeric microspheres. The present study provided a versatile approach for producing pure acetylenic polymeric microspheres due to the easy removal of the dispersing agent. The methodology showed significant practical potentials in preparing novel acetylenic polymer microspheres.