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PAMAM/[BMIM]PF6复合电解质的制备与性能

Preparation and Properties of PAMAM/[BMIM]PF6 Composite Electrolyte

中文摘要英文摘要

本实验研究了树枝状高分子PAMAM在1-丁基-3-甲基咪唑六氟磷酸盐离子液体([BMIM]PF6)中的物理混合,并制备了树枝状大分子/离子液体复合电解质,对其性能进行了系统研究,并分析了不同含量的离子液体对不同代数的树枝状大分子体系性能的影响。流变学测试表明,PF6离子液体和PAMAM共混后,粘度明显上升,其中PF6离子液体:PAMAM=1:10时,粘度达到最大。热稳定性能测试表明,随着离子液体含量的增加,体系的热稳定性能逐渐增加,当PF6离子液体:PAMAM为10:1、7:1和5:1的时候,体系比纯PF6离子液体表现出的相对热稳定性能还要高。离子电导率测试表明,体系导电率随着离子液体含量的增加而逐渐增加。

In this paper, the dendrimer/ionic liquid composite electrolyte was prepared by physical mixing mehtod, and its properties were systematically studied by using rheology, thermogravimetric analysis (TGA), and impedance analysis. Rheological tests show that the viscosity of the mixers significantly increased and viscosity reached the maximum when the ratio PAMAM/ionic liquid is 1:10. Thermal stability test shows that the thermal stability of the system increased gradually with the increase of the content of ionic liquids. The thermal stability of system is even higher than the pure ionic liquids when the ratio of ionic liquid/PAMAM excess 5:1. The ionic conductivity tests show that ionic conductivity increased gradually with the increase of the content of ionic liquids, and the ionic conductivity canreach 10-3 S/cm.

刘佳航、邱鹏、李晓冰、宋洪赞、孙岩、李美汐

电化学工业高分子化合物工业有机化学工业

树枝状高分子离子液体电解质

endrimerIonic liquidElectrolyte

刘佳航,邱鹏,李晓冰,宋洪赞,孙岩,李美汐.PAMAM/[BMIM]PF6复合电解质的制备与性能[EB/OL].(2016-05-23)[2025-08-11].http://www.paper.edu.cn/releasepaper/content/201605-972.点此复制

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