一叶萩碱与芳香醛的Baylis-Hillman反应研究
Study on Baylis-Hillman Reaction of Securinine with Some Aromatic Aldehydes
本文研究了一叶萩碱(securinine)与一些醛类化合物发生Baylis-Hillman反应的条件和结果。发现在无水乙醇为溶剂，甲醇钠催化的条件下，一叶萩碱的12位与14位能与芳香醛类发生Baylis-Hillman反应，并讨论了反应机理。
In this paper，the conditions of Baylis-Hillman reaction between securinine and aldehyde were investigated. The results suggested that in the condition of anhydrous ethyl alcohol and sodium methoxide, securinine could react with aromatic aldehyde smoothly on C-12 and C-14. Further more, the mechanism of this reaction was discussed.
陈卫民、刘鑫
有机化学工业
有机化学一叶萩碱芳香醛Baylis-Hillman反应
Organic chemistrySecurinineAromatic aldehydeBaylis-Hillman reaction
陈卫民,刘鑫.一叶萩碱与芳香醛的Baylis-Hillman反应研究[EB/OL].(2014-06-03)[2025-08-03].http://www.paper.edu.cn/releasepaper/content/201406-34.点此复制
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