新型立方烷四核镍配合物的合成、结构和低温磁性分析
he synthesis, structure and low-temperature magnetic behavior of the tetranuclear cubane-like [Ni4O4] complex
通过醋酸镍和手性席夫碱化合物（H2L）反应合成了一个新型的立方烷型四合镍配合物。X射线单晶衍射数据分析该化合物的立方烷核是由四个镍原子和四个醇氧原子交替形成。磁性数据显示其为铁磁相互作用。
tetranuclear cubane-like [Ni4(EtOH)3L4] (H2L= 2-((1-hydroxy-3-methylbutan-2- ylimino)methyl)phenol) complex has been prepared by the reaction of nickel(II) acetate with chiral Schiff base compound HBBBBB2BBBBBL. The X-ray crystal structure analyses revealed that the core of the cube formed by four Ni(II) ions and four alkoxide oxygen atoms at alternating corners. The temperature (2-300K) dependent magnetic susceptibility indicates it possesses a system with predominant ferromagnetic interaction.
梁倾、孙柏旺、陈晓丹、黄蓉
化学晶体学物理学
四核立方烷型镍配合物磁性
etranuclearubane-likeNickel complexMagnetic properties
梁倾,孙柏旺,陈晓丹,黄蓉.新型立方烷四核镍配合物的合成、结构和低温磁性分析[EB/OL].(2010-01-05)[2025-08-11].http://www.paper.edu.cn/releasepaper/content/201001-102.点此复制
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