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银修饰磷酸钒锂可见光催化降解水中氟虫腈研究

egradation of fipronil in water by silver modified lithium vanadium phosphate under visible light irradiation

中文摘要英文摘要

采用溶胶凝胶法和紫外光解法制备得到银修饰磷酸钒锂可见光催化剂,并通过X射线衍射技术证实了其结晶纯度和单斜结构。光催化剂的紫外可见吸收光谱扩展至720 nm,极大地提高了其可见光利用效率,其光生载流子的给出能力远高于传统的紫外光催化剂TiO2和可见光催化剂Bi2O3。实验结果表明,银修饰磷酸钒锂可见光催化剂的光能转化效率较高,在可见光及自然光照射下对水中典型的广谱杀虫剂氟虫腈具有较好的降解效果,光生电子对氟虫腈的降解起到了关键作用。?

In this study, silver modified lithium vanadium phosphate was prepared by sol-gel method and UV silver modification. The crystallization of silver modified lithium vanadium phosphate was confirmed by X-ray diffraction. The UV-visible absorption spectrum of silver modified lithium vanadium phosphate was extended to 720 nm, which greatly improves its absorptivity of visible light and enhanced the electron donating capacity, compared to traditional UV light driven photocatalyst nano-TiO2, and visible light driven photocatalyst Bi2O3. In the degradation of fipronil in aqueous solution, silver modified lithium vanadium phosphate exhibited high eifficiency for photocatalytic transformation of fipronil under visible light irradiation. Photo-generated electrons plays a key role on the degradation of fipronil in aqueous solution.

包月平、牛军峰、殷立峰

环境污染、环境污染防治化学无机化学工业

磷酸钒锂光催化氟虫腈可见光

Lithium vanadium phosphatePhotocatalysisFipronilSilverVisible light

包月平,牛军峰,殷立峰.银修饰磷酸钒锂可见光催化降解水中氟虫腈研究[EB/OL].(2014-04-18)[2025-08-06].http://www.paper.edu.cn/releasepaper/content/201404-255.点此复制

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