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atalytic Activity of Styrene-divinyl Benzene Supporting Metallophthalocyanine

atalytic Activity of Styrene-divinyl Benzene Supporting Metallophthalocyanine

中文摘要英文摘要

Binuclear cobalt phthalocyanine (Co2Pc2) was supported on styrene-divinyl benzene resin by covalent bond to obtain a novel catalytic functional material, Resin-Co2Pc2. The effects of pH, the quantity of Resin-Co2Pc2 and temperature on the catalytic activity of Resin-Co2Pc2 on 2-mercaptoethanol were investigated. The results showed that Resin-Co2Pc2 had high catalytic activity on 2-mercaptoethanol, and even the catalytic activity was the best at pH11. The reaction can further be enhanced with the quantity of Resin-Co2Pc2 and temperature increasing, due to its endothermic characteristics. There was no decrease in the catalytic activity of Resin-Co2Pc2 after five repetitive experiments, which indicated that Resin-Co2Pc2 could be recycled.

Binuclear cobalt phthalocyanine (Co2Pc2) was supported on styrene-divinyl benzene resin by covalent bond to obtain a novel catalytic functional material, Resin-Co2Pc2. The effects of pH, the quantity of Resin-Co2Pc2 and temperature on the catalytic activity of Resin-Co2Pc2 on 2-mercaptoethanol were investigated. The results showed that Resin-Co2Pc2 had high catalytic activity on 2-mercaptoethanol, and even the catalytic activity was the best at pH11. The reaction can further be enhanced with the quantity of Resin-Co2Pc2 and temperature increasing, due to its endothermic characteristics. There was no decrease in the catalytic activity of Resin-Co2Pc2 after five repetitive experiments, which indicated that Resin-Co2Pc2 could be recycled.

Wang Xiuhua、Huang Xianwen、Yao Yuyuan、Lv Wangyang、Chen Wenxing

有机化学工业高分子化合物工业合成树脂工业、塑料工业精细化学工业

binuclear cobalt phthalocyaninecatalytic oxidationfunctional materials2-mercaptoethanol

binuclear cobalt phthalocyaninecatalytic oxidationfunctional materials2-mercaptoethanol

Wang Xiuhua,Huang Xianwen,Yao Yuyuan,Lv Wangyang,Chen Wenxing.atalytic Activity of Styrene-divinyl Benzene Supporting Metallophthalocyanine[EB/OL].(2008-10-10)[2025-08-05].http://www.paper.edu.cn/releasepaper/content/200810-195.点此复制

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