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一种新型的基于石墨相氮化碳的光电传感器应用于草甘膦的检测

novel photoelectrochemical sensor based on graphitic carbon nitride for glyphosate detection

中文摘要英文摘要

基于结合诱导内移能够使信号On的策略,一种氮化碳修饰的银离子的光电传感应用于草甘膦的检测。石墨相氮化碳作为光敏材料具有很好的光电化活性,石墨相氮化碳骨架上的吡啶氮单元能够过化学吸附银离子,光生电子能够被银离子捕获,导致电子转移受阻,光电流降低。然而,银离子和草甘膦之间的螯合作用能够增强其信号。这种经济灵敏的传感体系能够广泛应用于物质检测。

A signal-on photoelectrochemical strategy with graphitic carbon nitride decorated Ag+ based on the binding-induced internal-displacement for glyphosate monitoring was established. graphite-like carbon nitride as visible light-active material possesses fine photocatalytic activity, the pyridine nitrogen units on g-C3N4 backbone could absorb Ag+ through chemical absorption and then photo-generated electrons would be reacted by Ag+, leading to the inhibition of electrons transfer and decrement of photocurrent. However, the chelate effect between Ag+ and glyphosate can promoted the constitution of current circuit and signal improvement. This economical and sensitive sensor system could be broadly applied for substance detection.

张书培、龚玲珊、李宜霖、戴宏、陈四红、徐桂芳、张清榕、严惠湘

农药工业环境生物学

光电化学传感器石墨相氮化碳银离子草甘膦螯合作用

photoelectrochemical sensorgraphitic carbon nitrideAg+glyphosatechelation

张书培,龚玲珊,李宜霖,戴宏,陈四红,徐桂芳,张清榕,严惠湘.一种新型的基于石墨相氮化碳的光电传感器应用于草甘膦的检测[EB/OL].(2015-11-10)[2025-08-11].http://www.paper.edu.cn/releasepaper/content/201511-129.点此复制

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