1-(2,4,6-三甲基)苯基-3-二环己基膦茚四氟硼酸盐的合成
Synthesis of 1-[1-(2, 4, 6-trimethyl)phenyl]indenyl-3- dicyclohexylphosphoium tetrafluoroborate
1-(2,4,6-三甲基)苯基茚与丁基锂反应生成阴离子,此阴离子与二环己基氯化膦进行位置专一性反应生成1-(2,4,6-三甲基)苯基-3-二环己基膦茚,此配体与四氟硼酸反应生成可在空气中稳定存在的1-(2,4,6-三甲基)苯基-3-二环己基膦茚四氟硼酸盐,所得化合物经波谱表征,并经单晶X-ray衍射确认。
eprotonation of 1-(2,4,6-trimethyl)phenyl indene by BuLi and trapping of the lithiated intermediate by dicyclohexylphosphine chloride afforded regiospecific 1-[1-(2,4,6-trimethyl)phenyl]indenyl-3- dicyclohexylphosphine as the only product, this phosphine ligand react with tetrafluoroborate acid give the air stable 1-[1-(2,4,6-trimethyl)phenyl]indenyl-3-dicyclohexylphosphoium tetrafluoroborate. The product has been fully characterized by spectroscopy, and X-ray crystal diffraction techniques.
刘盛华、夏建龙、张蓓、郝小伟、余广鳌
有机化学工业精细化学工业
有机化学位置专一性膦四氟硼酸盐合成
Organic chemistryRegiospecificPhosphineTetrafluoroborateSynthesis
刘盛华,夏建龙,张蓓,郝小伟,余广鳌.1-(2,4,6-三甲基)苯基-3-二环己基膦茚四氟硼酸盐的合成[EB/OL].(2011-01-14)[2025-08-05].http://www.paper.edu.cn/releasepaper/content/201101-770.点此复制
评论