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首页|快速热退火对GaAs/AlGaAs量子阱材料结构及光学特性的影响研究

快速热退火对GaAs/AlGaAs量子阱材料结构及光学特性的影响研究

Research on the Impact of Rapid Thermal Annealing on the Structure and Optic Character of GaAs/AlGaAs Quantum Well Material

中文摘要英文摘要

GaAs/AlGaAs量子阱材料是制备高性能激光探测器件的重要材料。然而材料在生长中引入的缺陷及材料的异质界面存在的界面特性,严重影响了光电器件的性能。而快速热退火(RTA)不仅可以使得材料重结晶,提高材料晶体质量,还可以促使量子阱材料界面混合,来达到改善量子阱的结构特性,使其带隙调谐,因此开展快速热退火对GaAs/AlGaAs量子阱材料结构及光学特性的影响研究。研究发现,当RTA 800℃后,XRD显示材料晶体质量和PL强度得到显著提升,是由于RTA消除了材料界面处存在的缺陷及位错,抑制了非辐射复合引起的。当RTA 900℃后,XRD显示材料晶体质量下降并且PL发光强度降低,是由于Al-Ga原子互扩散造成的界面混合引起的量子阱量子限制效应降低造成的,并且依据峰值能量理论计算,得到了室温下PL峰位的发光机制,通过分峰拟合后,发现快速热退火导致PL峰位整体蓝移,而Al-Ga原子的互扩散使得带间输运能量的增加,是造成室温PL整体峰位蓝移的主要原因。PL mapping显示了快速热退火可以显著改善材料整体发光均匀性,提高了材料整体质量。

GaAs/AlGaAs Quantum Well Material is an important material to produce high-performance laser devices. However, the defects introduced during material growth and interface characteristics existing in heterogeneous interface of the material severely influence the performance of optoelectronic devices. RTA (rapid thermal annealing), fortunately, not only can recrystallize the material and improve the crystal quality of the material, but also promote the mixing of quantum well material interface to improve the structural characteristic of quantum well, tuning the band gap. Research on the impact of RTA on the the structure and optic character of GaAs/AlGaAs quantum well material indicates that when the temperature of RTA reaches 800℃, XRD shows that the crystal quality of the material and PL strength is significantly improved due to the elimination of the defects and dislocations on the interface of the material and the suppression of the non-radiative recombination caused by RTA. When the temperature of RTA reaches 900℃, XRD shows that the crystal quality of the material and PL luminescence strength are reduced because of the reduced quantum confinement effect of quantum well as mutual diffusion of Al-Ga atoms makes interface mixed. Besides, according to the calculation of the peak energy theory, the luminescence mechanism of PL peak at room temperature is obtained, and the result of peak fitting indicates that RTA leads to the blue shift of the whole PL peak and that mutual diffusion of Al-Ga atoms increases the transport energy between band gaps, which is the main cause of the blue shift of PL peak. PL mapping suggests that RTA can significantly improve the overall luminescence uniformity and overall quality of the material.

蔡昕旸、牛守柱、魏志鹏、智民、房丹、方铉、王新伟、王晓华、王登魁、唐吉龙

半导体技术光电子技术晶体学

GaAs/AlGaAs量子阱界面互扩散快速热退火

GaAs/AlGaAsquantum wellsintersurficial diffusionrapid thermal annealing

蔡昕旸,牛守柱,魏志鹏,智民,房丹,方铉,王新伟,王晓华,王登魁,唐吉龙.快速热退火对GaAs/AlGaAs量子阱材料结构及光学特性的影响研究[EB/OL].(2017-10-26)[2025-08-05].http://www.paper.edu.cn/releasepaper/content/201710-88.点此复制

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