二氧化钛/木质素多孔碳负极材料的研究
he Study on Titanium Dioxide/Lignin Porous Carbon Anode Material
随着锂离子电池被广泛用于动力汽车和便携式电子设备等领域,急需开发安全性能和电化学性能更好的电极材料来满足需求。二氧化钛负极材料因其资源丰富、成本低、安全性好等特性而受到广泛关注,同时低电导性和导锂离子性限制了其商业化应用。本论文用木质素分级多孔碳材料(LHPC)来负载二氧化钛晶粒,制备了二氧化钛/木质素多孔碳复合负极材料,并且对其进行了各种物理性能和电化学性能表征,以期获得电化学性能优异的二氧化钛复合负极材料。结果表明二氧化钛/木质素多孔碳负极材料倍率性能优异,可逆比容量高,循环稳定性好,这主要归因于高导电性和高比表面的LHPC材料。
With the lithium ion batteries are widely used in vehicles and other portable electronic devices, urgent need to develop better security and electrochemical properties of the electrode material to meet the demand. Titanium dioxide anode materials have received widespread attention due to their high natural abundance, low cost, and good safety. However, its low electrical conductivity and lithium ion conductivity limit their commercial applications. In this paper, the titanium dioxide/lignin porous carbon anode material was prepared by loading titanium dioxide crystal particles onto the surface of the hierarchical porous carbon from lignin (LHPC). In addition, various physical performance tests and electrochemical performance tests were carried out in order to obtain titanium dioxide-based anode materials with excellent electrochemical properties. The results show that the titanium dioxide/lignin porous carbon composite exhibites perfect rate capability, a stable high capacity and excellent cycling stability as an anode material in Li-ion battery. The superior electrochemical properties of titanium dioxide/lignin porous carbon composite are mainly attributed to the perfect conductive carbon network and the high specific surface area of LHPC.
李文生、张海棠、周小平
电化学工业
锂离子电池负极材料二氧化钛
Li-ion batteryanode materialtitanium dioxide
李文生,张海棠,周小平.二氧化钛/木质素多孔碳负极材料的研究[EB/OL].(2021-05-18)[2025-08-02].http://www.paper.edu.cn/releasepaper/content/202105-107.点此复制
评论