u-TiO2复合材料的酸性制备及其光催化性能研究
cidic Preparation and Photocatalysis Performance of Au-TiO2 composites
本文在酸性条件下成功制备了具有不同金纳米颗粒负载量的Au-TiO2复合材料。光学表征表明,虽然在表面等离子-激子耦合的作用下,复合材料的吸收性能和载流子分离率均随着金纳米颗粒负载量的增加而单调增强,但其光催化性能并未表现出单调变化的趋势,而是金纳米颗粒负载量为1wt.%的复合材料具有最高的催化性能,其可见光照射5h的降解率比罗丹明B提升了82.1%。随后,光催化性能随负载量增加而降低的现象可能与复合材料中金纳米颗粒的聚集及其形成的电子陷阱有关。
u-TiO2 composites with different Au nanoparticle (Au NP) loadings have been successfully synthesized under an acid condition. The optical characterizations indicate that both absorption performance and carrier separation rate monotonically improved with the increasing of the Au NP loading in the composite due to the plasmon-exciton coupling. However, instead of monotonically changing, the highest photocatalytic activity had been achieved when the loading was 1wt.%, and the degradation rate exposuring to visible light about 5h of such composite is 82.1% higher than that of RhB.The following decreasing of the degradation rate with the increasing of the loading coulde be due to the the aggregation of Au NPs and thus formed electron traps.
杨浩、丁龙、查文杰、李淼、汪俊、张润泽、鲁颖炜
化学金属元素无机化合物化学工业电化学工业
复合材料表面等离子-激子耦合光催化性能
ompositePlasmon-exciton couplingPhotocatalytic performance
杨浩,丁龙,查文杰,李淼,汪俊,张润泽,鲁颖炜.u-TiO2复合材料的酸性制备及其光催化性能研究[EB/OL].(2020-05-06)[2025-08-10].http://www.paper.edu.cn/releasepaper/content/202005-13.点此复制
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