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纤维乙醇残渣Py-GC/MS催化热解实验研究

Experimental Research on Catalytic Pyrolysis of Cellulosic Bioethanol Residue using Py-GC/MS

中文摘要英文摘要

本文针对木质纤维乙醇炼制过程中产生的大量残渣,采用在线热解质谱-色谱分析仪(Py-GC/MS)进行了催化热解制备芳香烃的实验研究。首先考察了在单一大孔/中孔催化剂作用下,不同种类催化剂(CaO、FCC、CP814E等)对纤维乙醇残渣催化热解的影响。在此基础上,用两种催化剂(其中一种作为微孔沸石催化剂)进行催化热解实验。结果表明,断键催化剂能够实现初步脱氧,复合催化剂作用下更容易生成辛烷值更高的支链烃类。

large amount of residue was produced in cellulosic bioethanol production process. Catalytic pyrolysis of the residue to produce aromatics was carried out using Py-GC/MS in this paper. The effects of different kinds of large or medium pore catalysts (CaO, FCC, CP814E, et al) in catalytic pyrolysis were studied. On this basis, the mixture of two kinds of catalysts (including one microporous zeolite catalysts) was using for catalytic pyrolysis. The results of catalytic pyrolysis with single catalyst and mixed catalysts were well compared. The results showed that the bond breaking catalyst can preliminarily achieve deoxgenation. In addition, the mixed catalysts are more likely to generate higher octane number with more branched hydrocarbons production.

程志、康泰、张会岩、卞绍华、刘赜深、周琳绯

生物能、生物能机械设备燃料化学工业

生物质催化热解芳香烃

biomasscatalytic pyrolysisaromatics

程志,康泰,张会岩,卞绍华,刘赜深,周琳绯.纤维乙醇残渣Py-GC/MS催化热解实验研究[EB/OL].(2014-11-28)[2025-08-23].http://www.paper.edu.cn/releasepaper/content/201411-568.点此复制

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