枣阳低品位复杂金红石矿的浮选分离及与辛基羟肟酸相互作用机理
Flotation seperation of low grade and complex rutile ore in Zaoyang and interaction of rutile with octyl hydroxamic acid
通过实际矿石试验、纯矿物试验研究了枣阳金红石的浮选分离,并通过Zeta动电位测试、红外光谱测试进一步探索了辛基羟肟酸与金红石的作用机理。实际矿石试验表明,C5~9异羟肟酸和苄基胂酸(BAA)的混合捕收剂可以有效捕收金红石,浮选精矿达到43.25%,回收率为69.10%。单矿物试验表明,辛基羟肟酸(OHA)是金红石和钙铁榴石有效捕收剂,铅盐可以显著活化金红石而对钙铁榴石活化作用较弱。同时,研究发现氟硅酸钠是钙铁榴石有效的选择性抑制剂。Zeta电位测量和红外光谱的测量表明,辛基羟肟酸在金红石表面发生了化学吸附和物理吸附,并形成了稳定的五元螯合物。
he flotation separation of rutile ore in Zaoyang was investigated by raw ore experiments and pure mineral tests. The mechanism of rutile with octyl hydroxamic acid (OHA) as collector was further studied by Zeta potential measurement and Infrared spectrum measurement. Raw ore experiment results indicate that rutile can be recycled effectually by using C5~9 hydroxamic acid as collector. The rutile grading of flotation concentrate can reach to 43.25% with the recovery of 69.10%.The pure mineral tests indicate that octyl hydroxamic acid(OHA) is an effective collecter of rutile and andradite, and rutile can be activated remarkably by lead nitrate while andradite not. Sodium fluosilicate was found to be an effective selective depressor for andradite. Zeta potential measurements and Infrared spectrum measurements indicate chemisorption and physically absorption are occured on the surface of rutile with OHA and stable pentabasic chelate are formed.
刘贝、邱冠周、覃文庆、程宏伟、李开运、王军
选矿矿产资源综合利用
金红石,钙铁榴石,氟硅酸钠,浮选分离,红外光谱
rutileandraditesodium fluosilicateflotation separatinginfrared spectroscopy
刘贝,邱冠周,覃文庆,程宏伟,李开运,王军.枣阳低品位复杂金红石矿的浮选分离及与辛基羟肟酸相互作用机理[EB/OL].(2015-03-26)[2025-08-02].http://www.paper.edu.cn/releasepaper/content/201503-339.点此复制
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