增强相对无铅焊点电迁移行为影响的研究
he Effects of Reinforcement Phases on Electromigration Behaviors in Lead-free Solder Joint
微型化和多功能化的需求促使单个焊点所需承受的电流密度不断增加,这使得电迁移现象成为了重要的可靠性问题之一。焊点电迁移行为的抑制可通过结构优化和材料改性两种方法实现。本文从材料改性的角度出发,采用观察焊接接头显微组织演变的方法,分析和讨论了0.2wt.%Co元素的添加以及内生5vol.%Cu6Sn5相的方法对焊点电迁移行为的影响。结果显示,微量元素Co(0.2wt.%)的添加和内生Cu6Sn5(5vol.%)相的形成对于钎料接头的电迁移损伤具有有效的缓解作用。Co元素促使Ag3Sn相弥散分布形成Cu原子迁移的屏障,同时对于(Cu, Co)6Sn5的迁移起到钉扎作用。内生Cu6Sn5相在基体中的形成改变了界面处Cu原子的化学浓度梯度,从而抑制了Cu原子的迁移。
he requirements of miniaturization and multifunctional for microelectronic devices lead to the current density which imposes on the solder joint continuous increase. Therefore, electromigration (EM) is becoming a standout reliability issue for lead-free solder. Structural optimization and material modification are considered to be the possible methods for alleviating EM damage. This study investigates the impact of 0.2wt.% Co additions and in-situ 5vol.% Cu6Sn5 , which were introdued into solder matrix by alloying and fabricating composite solder approaches respectively, on electromigration from the perspective of material modification. The results indicated that both 0.2wt.% Co and in-situ 5vol.% Cu6Sn5 played an effective role in inhibiting EM behavior. Co element additions made Ag3Sn intermetallic compounds disperse homogeneously in solder matrix and as a barrier to Cu atoms diffusion. Moreover, (Cu, Co)6Sn5 phase migration was pinned by Co addition. In-situ Cu6Sn5 phase suppressed EM by changing the chemical concentration gradient of Cu atoms at the interface.
马立民、郭福、左勇、刘思涵、赵然
电子元件、电子组件材料科学
合金化复合钎料电迁移
lloyingCompositeElectromigration
马立民,郭福,左勇,刘思涵,赵然.增强相对无铅焊点电迁移行为影响的研究[EB/OL].(2013-07-05)[2025-08-16].http://www.paper.edu.cn/releasepaper/content/201307-88.点此复制
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