多相催化颗粒在超临界水流化床中流化特性模拟研究
Numerical study of fluidization characteristics of heterogeneous catalyst particles in supercritical water fluidized bed
当前,超临界水流化床气化制氢技术是煤/生物质清洁高效利用的一种有效手段。本文以多相催化剂颗粒作为超临界水流化床床料,模拟研究多相颗粒在超临界水中的3维流化特性。由于TFM方法精度较差,DPM方法对计算量巨大而难以实现3维多颗粒模拟,本文采用兼具计算精度和速度的CPFD方法,以0.3mm和0.5mm两种粒径的氧化铝颗粒为研究对象进行研究。模拟获得床层压降与表观流速关系曲线,发现当表观流速在最小流化速度和最小鼓泡流化速度之间时,两种Geldart B类颗粒处于均匀膨胀流化阶段,并且随颗粒粒径增加,最小流化速度和最小鼓泡速度的比值减小,表现出更为典型B类颗粒流化特征。在均匀膨胀流化阶段和双对数坐标下,床层平均空隙率与表观流速为线性关系。颗粒速度分布主要受流体速度影响,并在局部受气泡涡旋影响。
oal/Biomass gasification for producing hydrogen by supercritical water (SCW) fluidized bed is an efficient and clean way. In this paper,heterogeneous catalyst particles was used as bed materials and simulated in 3-dimension for the study of its fluidization characteristics in SCW. As the accuracy of TFM is poor, and the caculation resource demand of DPM is so huge that it cannot be competent for 3-demension simulation, a new numerical simulation method, CPFD, was applied to this study. Two kinds of aluminium oxide particles, with diameters of 0.3mm and 0.5mm, were investigated in this work. The simulation result shows that, though the two kinds of particle are categorized as Geldart B, a homogeneous expansion fluidization area is found in the range of the minimum fluidization velocity and the minimum bubbling fluidization velocity. What's more, as the particle diameter increases, the ratio of the two velocities above gets lower and the fluidized behavior becomes more like that of Group B. In homogeneous fluidization regime and double logarithmic coordinate, bed averaged voidage increases linearly with superficial velocity. Particle motion is mainly dominated by fluid phase and influenced by bubble vortice locally.
吴振群、赵骁、苏晓辉、金辉
氢能、氢能利用工程基础科学材料科学
多相催化颗粒超临界水数值模拟PFD
Heterogeneous catalyst particleSupercriticla waterNumerical simulationCPFD
吴振群,赵骁,苏晓辉,金辉.多相催化颗粒在超临界水流化床中流化特性模拟研究[EB/OL].(2016-05-27)[2025-07-18].http://www.paper.edu.cn/releasepaper/content/201605-1411.点此复制
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