壳聚糖共价接枝碳纳米管/羟基磷灰石骨组织工程材料的制备及表征
Preparation and characterization of chitosan-covalently grafted multiwalled carbon nanotubes/hydroxyapatite composite for bone tissue engineering
本文采用壳聚糖共价接枝碳纳米管结合原位沉淀法制备了壳聚糖-碳纳米管/羟基磷灰石复合材料。通过红外光谱分析,证明了壳聚糖与碳纳米管之间通过共价键连接。对比未添加碳纳米管的壳聚糖/羟基磷灰石复合材料,壳聚糖-碳纳米管/羟基磷灰石复合材料的力学性能得到明显提高。碳纳米管的加入对复合材料中的无机粒子的形貌有着明显的调控作用,呈现出比较均一的纳米棒状结构。研究表明:碳纳米管增强相的加入以及共价接枝方法对碳纳米管与壳聚糖两相间结合力的提高,是复合材料力学性能提高的主要因素。
In this paper, a novel chitosan-grafted multiwalled carbon nanotubes/hydroxyapatite (CS-MWNTs/HA) composites were prepared through covalently grafting CS onto the surfaces of MWNTs and in-situ precipitation method. Fourier transform infrared spectroscopy analysis showed that CS was covalently grafted onto MWNTs. The addition of MWNTs can make the CS-MWNTs/HA composites resist significantly higher stress and greatly influenced the morphology of inorganic particles. The inorganic particles exhibited as nanosized rods with uniform particle size.The studies show that the stress of the composites was improved by the addition of MWNTs and the effect of good interfacial bonding between MWNTs and CS through covalent modification.
童华、陈黎、沈新宇、胡静晓
材料科学生物工程学
羟基磷灰石碳纳米管壳聚糖共价接枝
hydroxyapatitemuliwalled carbon nanotubeschitosancovalent grafting
童华,陈黎,沈新宇,胡静晓.壳聚糖共价接枝碳纳米管/羟基磷灰石骨组织工程材料的制备及表征[EB/OL].(2012-09-28)[2025-08-10].http://www.paper.edu.cn/releasepaper/content/201209-323.点此复制
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