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熵增原理和熵增率极小原理的辩证统一

ialectical unity between principle of maximum entropy and principle of minimum entropy increase rate

中文摘要英文摘要

由于没有充分注意通过形式语言严格表述的热力学有限论域,在热力学平衡态和热力学动力过程的形式定义,Gibbs-Duhem方程是否具有普适意义等一系列基本问题方面,长时间存在着争论以及争论中的逻辑不自洽现象。除了对这些基本概念给予重新诠释,本文独立提出适用于动力学过程的熵增率最小原理。局限于热力学有限论域,动力学过程熵增率最小定理与恒定状态下的极大熵原理是两个具有独立意义和彼此逻辑相容的变分原理。正是它们相互约束与相互依存的辩证统一,为人们理性和逻辑自洽地描述宏观物质世界的复杂现象提供了基础。

It has been neglected to build a finite discourse universe for thermodynamics by though strict formal language. A series of fundamental problems, as such as what both the formal definitions of thermodynamics equilibrium state and thermodynamics dynamical course are, whether Gibbs-Duhem equation is of general significance, has not really resolved. And some paradoxes implicated in the relative disputations. Besides supplying fresh interpretations on them, this paper constructs a minimum principle of entropy increase rate used in complex dynamic process and, limited within thermodynamics region, which and the maximum entropy principle used in complex stationary state are two independent and consistent principles. And, it is just the dialectical unity of both the principles, relying upon each other, that provides a foundation for people to rationally describe the complex phenomena of macroscopic material world.

杨本洛

物理学

平衡态,动力学过程,Gibbs-Duhem方程,复杂现象,熵,熵增率,极值原理

equilibrium state dynamic process Gibbs-Duhem equation complex phenomenon entropy entropy increase rate extremum principle

杨本洛.熵增原理和熵增率极小原理的辩证统一[EB/OL].(2006-05-26)[2025-08-23].http://www.paper.edu.cn/releasepaper/content/200605-335.点此复制

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