轴不安定手性配体的开发及其在不对称催化反应中的应用
evelopment of Axial-unfixed (Tropos) Ligands and Their Applications in Asymmetric Catalytic Reactions
轴不安定配体应用于不对称催化有其独到的特点,不同于传统的轴安定手性配体。本文综述了轴不安定的噁唑啉、双膦、单膦、双羟基及N-O等配体的开发及其在不对称催化中的应用。
ropos ligands, compared with traditional atropos ligands, have unique characteristics. Here, the development of several major types of tropos ligands, including oxazoline, biphosphine, monophosphine, bihydroxyl and N-O ligands, and their applications in asymmetric catalysis have been reviewed.
王飞军、张万斌、杨国强、张勇健、戴轶俊
化学
轴手性轴不安定配体不对称催化
axial chiralityaxial-unfixed ligandsasymmetric catalysis
王飞军,张万斌,杨国强,张勇健,戴轶俊.轴不安定手性配体的开发及其在不对称催化反应中的应用[EB/OL].(2007-09-28)[2025-08-11].http://www.paper.edu.cn/releasepaper/content/200709-617.点此复制
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