具有“柱-层”结构的三维配位聚合物{[Cu2(bpta)(4,4'-bipy)]•(H2O)3}n的合成与结构表征
Synthesis and Characterization of 3D Pillared Metal-Organic Frameworks {[Cu2(bpta)(4,4'-bipy)]o(H2O)3}n
本文采用水热法以2,2',6,6'-联苯四甲酸和4,4'-联吡啶为配体和硝酸铜反应合成了一个新型的具有"柱-层"结构的配位聚合物{[Cu2(bpta)(4,4'-bipy)]?(H2O)3}n ],利用红外光谱、元素分析、热重及X-射线单晶结构分析对其进行了表征,证明了它的结构。
'pillar-layer' structure coordination compound of the formulas {[Cu2(bpta)(4,4'-bipy)]?(H2O)3}n ] (H4bpta = 1,1'-biphenyl-2,2',6,6'-tetracarboxylic acid and 4,4'-bipy = 4,4'-bipyridine) was synthesized and characterized by element analysis, IR, and X-ray single-crystal diffraction.
张大帅、田丹、吕迎彬、常泽
晶体学无机化学工业
配位聚合物“柱-层”结构水热合成
oordination polymerPillar-layer structureHydrothermal syntheses
张大帅,田丹,吕迎彬,常泽.具有“柱-层”结构的三维配位聚合物{[Cu2(bpta)(4,4'-bipy)]•(H2O)3}n的合成与结构表征[EB/OL].(2012-02-16)[2025-07-18].http://www.paper.edu.cn/releasepaper/content/201202-516.点此复制
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