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Antiferromagnetism of Double Molybdate LiFe(MoO$_4$)$_2$

Antiferromagnetism of Double Molybdate LiFe(MoO$_4$)$_2$

来源:Arxiv_logoArxiv
英文摘要

The magnetic properties of the spin-5/2 double molybdate LiFe(MoO$_4$)$_2$ have been characterized by heat capacity, magnetic susceptibility, and neutron powder diffraction techniques. Unlike the multiferroic system LiFe(MoO$_4$)$_2$ which exhibits two successive magnetic transitions, LiFe(MoO$_4$)$_2$ undergoes only one antiferromagnetic transition at $T_N$ ~ 23.8 K. Its antiferromagnetic magnetic structure with the commensurate propagation vector k = (0, 0.5, 0) has been determined. Density functional theory calculations confirm the antiferromagnetic ground state and provide a numerical estimate of the relevant exchange coupling constants.

Yunlong Xie、Fei Liu、Yu Wang、T. Charlton、V. Ovidiu Garlea、Jun-Ming Liu、Tao Zou、Yang Zhang、Biwen Li、Xiang Li、Xiuzhang Wang、Lun Yang、Meifeng Liu、Shuai Dong

10.1021/acs.inorgchem.0c00432

物理学晶体学

Yunlong Xie,Fei Liu,Yu Wang,T. Charlton,V. Ovidiu Garlea,Jun-Ming Liu,Tao Zou,Yang Zhang,Biwen Li,Xiang Li,Xiuzhang Wang,Lun Yang,Meifeng Liu,Shuai Dong.Antiferromagnetism of Double Molybdate LiFe(MoO$_4$)$_2$[EB/OL].(2020-07-20)[2025-08-02].https://arxiv.org/abs/2007.09936.点此复制

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