Microstructures and Dynamics of Tetraalkylphosphonium Chloride Ionic Liquids

Atomistic simulations have been performed to investigate the effect of aliphatic chain length in tetraalkylphosphonium cations on liquid morphologies, microscopic ionic structures and dynamical properties of tetraalkylphosphonium chloride ionic liquids. The liquid morphologies are characterized by sponge-like interpenetrating polar and apolar networks in ionic liquids consisting of tetraalkylphosphonium cations with short aliphatic chains. The lengthening aliphatic chains in tetraalkylphosphonium cations leads to polar domains consisting of chloride anions and central polar groups in cations being partially or totally segregated in ionic liquid matrices due to a progressive expansion of apolar domains in between. Prominent polarity alternation peaks and adjacency correlation peaks are observed at low and high $q$ range in total X-ray scattering structural functions, respectively, and their peak positions gradually shift to lower q values with lengthening aliphatic chains in tetraalkylphosphonium cations. The charge alternation peaks registered in intermediate q range exhibit complicated tendencies due to the complete cancellations of peaks and anti-peaks in partial structural functions for ionic subcomponents. The particular microstructures and liquid morphologies in tetraalkylphosphonium chloride ionic liquids intrinsically contribute to distinct dynamics characterized by translational diffusion coefficients, van Hove correlation functions, and non-Gaussian parameters for ionic species in heterogeneous ionic environment. The increase of aliphatic chain length in tetraalkylphosphonium cations leads to concomitant shift of van Hove correlation functions and non-Gaussian parameters to larger radial distances and longer timescales, respectively, indicating the enhanced translational dynamical heterogeneities of tetraalkylphosphonium cations and the corresponding chloride anions.