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改性草浆碱木素减水剂

Synthesizing of modified straw pulp lignin based plasticizer

中文摘要英文摘要

为开发利用草浆碱木素,通过引发氧化和磺化制备了改性草浆碱木素减水剂(MLP),测定了MLP的红外光谱、MLP在水泥颗粒表面的吸附量、水泥ζ-电位、MLP水溶液的表面张力及掺MLP的水泥净浆流动性,并测定了掺MLP的混凝土性能。草浆碱木素经氧化改性和磺化改性后,表面活性明显提高,使水的表面张力由70 mN/m下降到41 mN/m,通过吸附-分散作用,降低水泥颗粒的ζ-电位,分散水泥颗粒;掺MLP的混凝土性能符合高效减水剂标准要求,减水率达到15.2%,不仅可代替木浆木质素磺酸盐使用,而且因其具有高效减水剂的性能指标,还可作为高效减水剂使用,或部分取代常规萘系高效减水剂。

In order to use straw pulp lignin to produce water reducer of concrete, the solicitation oxidation, sulphonation processing and technical parameters for preparation chemical modified straw pulp lignin plasticizer (MLP) were investigated, and the characteristics of MLP were evaluated by measuring its IR spectrum, adsorbed amount on cement grains, zeta potential of cement and surface tension of MLP water solution. In addition, the properties of concrete plasticized with MLP were tested. Experimental results indicate that a kind of lignosulphonate, which has a water reducing rate of 15.2%, with —OH and —SO3 groups, can be obtained by oxidation and sulphonating straw pulp lignin, and that MLP has better adsorption-dispersion ability to cement grains by electrostatic repulsion. MLP may reduce surface tension of water. The properties of concrete plasticized with MLP accord with Chinese standard. As a kind of high range water reducer, MLP may replace lignosulphonates and partially replace naphthalene sulphonated formaldehyde condensates to be used in concrete.

张思佳、杨培杰、蒋亚清

高分子化合物工业精细化学工业纤维素化学工业

土木工程材料混凝土外加剂减水剂改性木质素磺酸盐草浆碱木素

civil engineering materialsconcrete admixturewater reducermodified lignosulphonatestraw pulp lignin

张思佳,杨培杰,蒋亚清.改性草浆碱木素减水剂[EB/OL].(2009-04-24)[2025-08-16].http://www.paper.edu.cn/releasepaper/content/200904-786.点此复制

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