新型FePt石墨纳米囊的合成及其作为甲醇燃料电池催化剂性能的应用
Synthesis of novel graphene encapsulated FePt nanoparticle as a direct methanol fuel cell catalyst
本文采用化学气相沉积(CVD)法一步合成了石墨烯(Graphene)包裹的FePt纳米囊并利用该颗粒(G-FePt)作为直接甲醇燃料电池的电极催化剂。该方法简单,方便,合成的纳米囊稳定且尺寸可控并兼具贵金属的优良催化效果及石墨烯良好的电学性能。在经过TEM,XRD等材料学表征后考察了其在甲醇氧化模型中的循环伏安电化学催化性能以及稳定性。该纳米囊表现出了良好的催化性能以及稳定性,为燃料电池催化剂提供了新的选择。
In this work, we synthesized a graphene encapsulated FePt nanoparticle (G-FePt) through a simple one-step CVD method. The G-FePt is stable and size controllable. This nanoparticle integrated the excellent catalysis ability of noble metal with the superior electronic properties of graphene. After comprehensive characterization such as TEM, XRD, its electrocatalytic performance and stability were investigated in the methanol oxidation model using cyclic voltammetry. The G-FePt showed very good catalytic capacity and stability, which makes it a promising candidate for the future fuel cell catalyst development.
宋志灵、丁玎、陈卓
氢能、氢能利用电化学工业燃料化学工业
电化学催化石墨烯FePt纳米囊燃料电池
ElectrocatalysisGrapheneFePt nanoparticleFuel cell
宋志灵,丁玎,陈卓.新型FePt石墨纳米囊的合成及其作为甲醇燃料电池催化剂性能的应用[EB/OL].(2014-12-30)[2025-08-05].http://www.paper.edu.cn/releasepaper/content/201412-975.点此复制
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