微波频率下氯化钠溶液电导率的非线性特性
Nonlinear Characteristics of Conductivity in Aqueous NaCl Solution at Microwave Frequency
在微波频段研究了电磁场对氯化钠溶液电导率的影响.运用不对称周期双阱势函数和Langvin方程描述了恒温条件下氯化钠溶液团簇结构中平均氢键的动力学行为,由Bertolini公式建立团簇的平均氢键形成的概率变化与电导率变化的关系.计算结果表明,在恒温条件下,当微波场的场强达到104V•m-1时,微波能会部分转化为团簇里分子间势能,使得氯化钠溶液的电导率与电场强度有关,这一结果与实验结果符合.这种微波与氯化钠溶液的相互作用表现出强烈的非线性变化,应该属于微波的非热效应范畴.
he influence of electromagnetic fields on conductivity of aqueous NaCl Solution at microwave frequency was studied.The Langvin equation was performed by using an asymmetrical double-well and periodic potential.All runs were started from describing the average hydrogen-bond of cluster configuration in aqueous NaCl solution under the constant temperature conditions.The relation between the conductivity and the probability of hydrogen bonding formation was established by using Bertolini function.When the intensity of microwaves was above 104 V•m-1,the calculation indicated that microwave energies were partly transformed to intermolecular energies of cluster,which made conductivity interrelated on intensity of microwave.The results agreed well with experiments.The strongly nonlinear changed categorized as one of microwave nonthermal effects.
黄卡玛、贾国柱、杨晓庆
电工基础理论物理学
微波氯化钠水溶液Langvin方程团簇氢键非热效应
MicrowavesAqueous NaCl solutionLangvin equationClusterHydrogen-bondNonthermal effects
黄卡玛,贾国柱,杨晓庆.微波频率下氯化钠溶液电导率的非线性特性[EB/OL].(2008-01-03)[2025-08-10].http://www.paper.edu.cn/releasepaper/content/200801-84.点此复制
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