以正戊烷沥青质含量为参数的温拌沥青老化动力学研究
ging Kinetics Study of Warm mix asphalt using the content of n-pentane asphaltene as the parameter
在不同老化温度和老化时间下,对温拌沥青、基质沥青进行了老化试验,测试了老化前后沥青中正戊烷沥青质含量的变化,建立了以正戊烷沥青质含量为参数的老化动力学模型,计算了老化反应速率常数和老化反应活化能等老化动力学参数,对比研究了温拌沥青与基质沥青的老化动力特性。研究结果表明:沥青老化遵循一级反应动力学方程,老化过程中正戊烷沥青质含量均随时间的延长和温度的升高而增大,而温拌沥青具有较低的反应速率常数和较高的反应活化能,因此抗老化性能更好。以正戊烷沥青质含量为参数的老化动力学方程,能够较好地区分温拌沥青与基质沥青老化过程的差异。
he aging tests of warm mix asphalt and matrix asphalt are conducted at different temperatures and time, and the contents of n-pentane asphaltene of aged asphalts are measured. By taking the content of n-pentane asphaltene as the parameter, the aging kinetics models are established for the two asphalts, and the reaction constants and reaction activation energies are calculated. It is indicated that the aging process of the two asphalts follows the first-order kinetics reaction equation, and the content of n-pentane asphaltene increases with the aging temperature and aging time. The reaction constant of warm mix asphalt is lower, but the reaction activation energy is bigger than matrix asphalt, that is to say the anti-aging property of warm mix asphalt is better. The aging kinetics models based on the content of n-pentane asphaltene could be used to distinguish the different aging processes of warm mix asphalt and matrix asphalt well.
裴建中、徐士翠、张久鹏、杜慧
石油天然气加工石油天然气储运石油天然气工业经济
温拌沥青老化动力学正戊烷沥青质反应速率常数反应活化能
warm mix asphaltaging kineticsn-pentane asphaltenereaction constantreaction activation energy
裴建中,徐士翠,张久鹏,杜慧.以正戊烷沥青质含量为参数的温拌沥青老化动力学研究[EB/OL].(2014-04-02)[2025-08-18].http://www.paper.edu.cn/releasepaper/content/201404-39.点此复制
评论