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黄原胶-丙烯酰胺接枝共聚物对Cr3+的吸附性能研究

dsorption properties of graft copolymers of Xanthan gum and acrylamide for Cr3+

中文摘要英文摘要

以黄原胶为原料,丙烯酰胺为接枝单体,采用微波辐射聚合得到了黄原胶-丙烯酰胺接枝共聚物(XG-g-AM),利用红外光谱仪、X射线衍射仪对其结构进行表征。研究了 XG-g-AM对Cr3+的静态吸附行为,并根据吸附等温线研究了吸附热力学性质,结果表明:在研究的浓度范围内,XG-g-AM对Cr3+的吸附行为可用Freundlich等温式进行描述;吸附为自发的、吸热的熵增加过程,升高温度有利于吸附。

he graft copolymers of Xanthan Gum and Acrylamide (XG-g-AM) were synthesized from Xanthan Gum by microwave irradiation with acrylamide as grafted monomer. XG-g-AM were characterized by Fourier t0ransform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). Adsorption behavior of XG-g-AM for Cr3+ was investigated, moreover, thermodynamics property was studied according to adsorption isotherm. The results show that the adsorption behavior of XG-g-AM for Cr3+ is adapted to Freundlich adsorption isotherm equation when temperature were in the range of 298 to 318K. The adsorption is a spontaneous and endothermic process of increased entropy, and the increase of temperature would benefit the adsorption.

王磊、李仲谨、诸晓锋、程磊

环境污染、环境污染防治高分子化合物工业生物工程学

XG-g-AM吸附r3+热力学

XG-g-AMdsorptionr3+hermodynamics

王磊,李仲谨,诸晓锋,程磊.黄原胶-丙烯酰胺接枝共聚物对Cr3+的吸附性能研究[EB/OL].(2009-04-24)[2025-05-14].http://www.paper.edu.cn/releasepaper/content/200904-796.点此复制

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