醇类添加剂对冷冻浇注陶瓷的多孔结构及形貌的影响
?Effect of alcohol additives on the pore structure and morphology of the freeze-cast ceramics
本研究采用冷冻浇注法制备了具有层状多孔结构的氧化铝陶瓷。通过添加乙醇和正丙醇两种类型的醇类改变水的凝固点,研究了醇类的添加量及浆料的固态含量对水基氧化铝浆料的粘度,多孔陶瓷的微观结构,孔隙率和机械性能的影响。结果表明:随着浆料中乙醇和正丙醇含量的增加,浆料的粘度和氧化铝陶瓷的孔隙度增加;醇类的加入会使片层之间具有较好的连接性从而增加多孔氧化铝陶瓷的抗压强度;当乙醇或正丙醇的添加量为30 wt. %,对应的孔隙度最低,分别为68.52 %和73.72%,而抗压强度最高,分别为18.2 MPa和15.0 MPa。
he porous alumina ceramics with lamellar structure were fabricated successfully by freeze casting. The viscosities of alumina slurries, pore structures, porosities and mechanical properties of the sintered ceramics were investigated by introducing both types of alcohols as water solidification modifier into the initial slurries, such as ethanol and 1-propanol. With the addition of ethanol or 1-propanol, the viscosities of slurries and porosities of sintered ceramics increased. The compressive strengths of the sintered porous alumina ceramics were improved due to a good connectivity between lamellae with the addition of both types of alcohols. The lowest porosities of 68.52 % and 73.72 % and highest compressive strengths of 18.2 MPa and 15.0 MPa were obtained by the addition of 30 wt. % ethanol and 1-propanol, respectively.
张妍、周科朝、曾婧、张斗
材料科学硅酸盐工业有机化学工业
无机非金属材料氧化铝陶瓷多孔材料乙醇正丙醇
Inorganic nonmetallic materialsAlumina ceramicporous materialethanol1-propanol
张妍,周科朝,曾婧,张斗.醇类添加剂对冷冻浇注陶瓷的多孔结构及形貌的影响[EB/OL].(2013-07-26)[2025-08-16].http://www.paper.edu.cn/releasepaper/content/201307-363.点此复制
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