以4A沸石为载体的含铁Fenton催化剂的制备及性能研究
he preparation and Fenton performance of 4A zeolite supported iron oxide
Fenton技术作为高级氧化技术的一种,被认为是处理难生物降解类污水最有前景的技术之一。但Fenton反应存在如反应过程所需pH过低,铁物种大量消耗以及双氧水利用效率低等缺陷。本文以4A沸石基质,采用共沉淀和离子交换的方法,制备铁负载的4A沸石Fenton催化剂。通过扫描电镜(SEM)、傅里叶红外光谱(FTIR)、X射线光电子能谱(XPS)等技术对含铁沸石Fenton催化剂进行了结构性能表征,并通过对苯酚的降解性能来评估制备催化剂的催化性能。实验结果显示,与相应的铁氧化物相比,尽管以4A沸石为支撑体的Fenton催化剂具有较差的催化性能,但是该催化剂在催化过程中铁泄露量明显低于铁氧化物催化剂,证明该催化剂具有良好的稳定性,有利于该催化剂在实际过程中的应用。
Fenton reaction, as a kind of advanced oxidation technology, is considered to be one of the most promising technologies for the treatment of sewage. But Fenton reaction have the defects that limit its practical application, such as low pH, the need of stoichiometric amounts of iron salts and low efficiency of hydrogen peroxide. In this paper, a Fenton catalyst-4A zeolite supported iron oxide was prepared with the co-precipitation and ion exchange. The structure of the catalyst was characterized by scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and its catalytic performance was evaluated by the phenol degradation experiments. The results showed that, compared with the corrpesponding iron oxides, the catalysts displayed lower efficiency for phenol degradation, but it showed outstanding stability confirmed by its lower iron leaching. This results indicated the potential application of this catalyst for wastewater treatment.
李泓、朱祝华、娄立国、王丽玉、张磊、张玉忠、赵莉芝
环境污染、环境污染防治化学无机化学工业
污水处理Fenton反应过氧化氢4A沸石铁氧化物
Wastewater treatmentFenton reactionHydrogen peroxide4A zeoliteIron oxide
李泓,朱祝华,娄立国,王丽玉,张磊,张玉忠,赵莉芝.以4A沸石为载体的含铁Fenton催化剂的制备及性能研究[EB/OL].(2015-11-30)[2025-08-23].http://www.paper.edu.cn/releasepaper/content/201511-765.点此复制
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