童亭煤分次萃取及萃取物分析
nalysis of Extracts from Tong ting Coal by Fractional Extraction
为探索童亭煤中可溶小分子溶出行为,采用正己烷溶剂对童亭煤进行分次萃取,并对各次萃取物进行GC和FTIR分析,结果表明:童亭煤的累积萃取率与累积萃取时间呈对数函数关系。可溶小分子的种类在萃取的初期和末期均较多,但数量差异很大,前者主要为游离态小分子,而后者主要为微孔嵌入态小分子,且在溶出过程中分子量稍大的微孔嵌入态小分子比分子量稍小的微孔嵌入态小分子优先溶出。童亭煤的各次萃取物中主要富集含脂肪族成分,且溶出的含芳香族成分的小分子的缩合程度比较高。童亭煤红外光谱定量分析表明各特征官能团随累积萃取时间均呈波形变化。
In order to investigate the universalism and specialty of the solubilization behavior of small organic molecules in coal, Tong ting coal was extracted with N-hexane in batches. N-hexane soluble components was analyzed by GC and FTIR. The results show that: The relationships between the curves of accumulative extraction yield and the Cumulative time is a Logarithmic function ; Soluble small molecules will be greater dissolution in the initial and late of the Extraction, but the numbers is very different, the former mainly free state small molecules and later period mainly micropore-inbuilt state- small molecules, In the process of dissolution , weight big member The molecular weight great molecular of the micropore-inbuilt state–molecules proportion small dissolves first; In the extract gained contains the aliphatic compound richly and Aromatic compound\
侯翠利、巩涛、李兴顺
煤化学、煤的加工利用
煤分次萃取GCFTIR
coalfractional extractionGCFTIR
侯翠利,巩涛,李兴顺.童亭煤分次萃取及萃取物分析[EB/OL].(2009-06-15)[2025-08-05].http://www.paper.edu.cn/releasepaper/content/200906-435.点此复制
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